Mechanistic Studies of Oxygen Activation and Atom Transfer Reactions with Mononuclear Vanadium(III), Iron(II), and Palladium(0) Complexes.

Palluccio, Taryn.


  • Abstract: This thesis comprises the area of oxygen binding, activation, and related oxygen atom transfer processes promoted by mononuclear transition metal complexes of vanadium(III), iron(II), and palladium(0). The first part of this thesis details the mechanistic studies of ligand binding and oxygen atom transfer (OAT) reactions to the three-coordinate complex VIII(N[tBu]Ar)3 (Ar = 3,5-Me2C6H3).... read more
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