Iron(II) Aminopyridine Macrocycles in Catalytic Oxidations: Structures, Reactivity, and Mechanistic Studies of Reactive Intermediates.

Ye, Wanhua.


  • Abstract: This document comprises the results of research in the area of olefin epoxidation with new aminopyridine iron(II) macrocycles: identifying structural features and mechanistic studies of reactive intermediates. Advances in our understanding of the mechanistic role of Fe(IV)-oxo intermediates of non-heme iron enzymes, and the accessibility of similar iron(IV) intermediates in synthetic mod... read more
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