Exploring Exceptions to the Sulfonate-Mediated Dehydrative Glycosylation Using L-Digitoxose as a Model

Chan, Keith Chi-Ki

2023

Description
  • The Bennett lab’s glycosylation methodology usually produces β-selective linkages. However, more recent works have suggested that if the substituent of the donor at C3 switches from an equatorial position to axial, the same glycosylation conditions favor the opposite α-selectivity. In this thesis, I hypothesize that the axial C3-substituents are directly responsible for the observed α-selectivity, ... read more
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