A Sci(l)ence of Three Parts: Synthesis, Characterization, and Oxidation Catalysis Studies of Bleomycin-Inspired Monofunctionalized Iron, Copper and Cobalt Pyridine-Azamacrocycles

McKenzie, Severin.


  • Abstract: Iron, copper, and cobalt metal complexes of the pyridine-aza macrocyclic (PyMac) ligand, CRH's propionic acid-functionalized derivatives (deemed MLCOOH) were synthesized, characterized via X-Ray crystallography and various spectroscopic techniques, and assessed for their olefin epoxidation and phenol/catechol oxidation capabilities. The various metal complexes exhibited a tradeoff betwee... read more
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