Tackling the glycosylation of 2-deoxy-sugars: A reagent-controlled approach utilizing cyclopropenium cations for the α-selective glycosylations of 2-deoxy-, 2,6-dideoxy- and 2,3,6-trideoxy-sugars

Nogueira, Jason.


  • Abstract: Gaining access to stereodefined deoxy-sugar containing oligosaccharides, such as those containing 2,6-dideoxy and 2,3,6-trideoxy motifs, remains a formidable challenge. This is largely due to the difficulties associated with controlling the selectivity of glycosylations using deoxy-sugar donors. Herein, the development of three generations of reagent-controlled approaches utilizing cyclo... read more
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