Aromatic hydroxylation at a non-heme iron center: insights into the nature of metal-based oxidant.

Makhlynets, Olga.
2017-04-18T14:01:12.944Z

Abstract: Mechanism of substrate oxidations with hydrogen peroxide in the presence of highly reactive biomimetic aminopyridine iron compex, [FeIIBPMEN(CH3CN)2](ClO4)2 (1), is elucidated. 1 has been shown to be an excellent catalyst for epoxidation and functional group- directed aromatic hydroxylation using H2O2, although its mechanism of action remains largely unknown.[1, 2] Efficient intermolecul... read more

Subjects
Tufts University. Department of Chemistry.
Permanent URL
http://hdl.handle.net/10427/011449
ID: tufts:20924
To Cite: DCA Citation Guide